Target complex Programme for Research of NAS UKRAINE

«Development of scientific bases for hydrogen production, storage and use in autonomous energy supply systems»


Home

Program projects

On the most important:


Autonomous catalytic generator of hydrogen from biological raw materials

Autonomous

Area of application

Hydrogen supply systems for autonomous power generating devices based on fuel cells.

Brief description

The project aims to develop catalysts and a portable reactor for heterogeneous-catalytic conversion of bioethanol for its use as an autonomous hydrogen generator for the operation of hydrogen fuel cells

Expected results

Determination of the composition and method of preparation of catalysts and conditions for obtaining the hydrogen with required purity by catalytic steam reforming of bioethanol in a portable reactor for autonomous hydrogen-based energy supply systems and low-temperature fuel cells based on renewable sources of raw materials.

Advantages

Autonomous catalytic hydrogen generator provides the possibility of hydrogen production on the basis of renewable raw materials (bioethanol) as an alternative to processes using fossil fuels, in particular methane. The proposed catalysts are capable of providing a high degree of ethanol conversion and selectivity for hydrogen production, contain no noble metals, have a carbonization resistance and do not require additional hydrogen costs for the reduction of the active metal phase.

Competitor

The process is not commercialized today. Investigations in the area of catalytic steam reforming of ethanol are carried out in scientific centers in several European countries (France, Italy, Spain, Greece, Hungary), USA, Brazil, China and Japan.

Project development

It were developed the prospective initial catalytic systems based on ferrites Mg, Mn and Fe, which are characterized by thermal stability of the oxide phase, have shown significant catalytic activity and selectivity in the process of hydrogen production by steam reforming of liquid oxygenates derived from biomass.

Intellectual property

  • Process for the preparation of hydrogen. Ukrainian Patent number 60806, published 25.06.2011, Bulletin No 12
  • Catalyst for hydrogen preparation by steam reforming of ethanol. Ukrainian Patent number 115288, published 10.04.2017, Bulletin No 7

    Contact information

    L.V.Pysarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine

    Project 6 «Autonomous catalytic generator of hydrogen from biological raw materials»

    Project leader:

    Strizhak Peter

    project leader
    Corresponding Member of NAS of Ukraine
    professor
    Doctor of Chemical Sciences
    Head of the Division of Catalytic Syntheses Based on Single Carbon Molecules

    Tel. +38 044 525-66-63

    Е-mail: pstrizhak@hotmail.com