Conferences

MECHANICAL AND FUNCTIONAL PROPERTIES OF COMPOSITE COATINGS WITH FINE REINFORCEMENTS  PRODUCED FROM GALVANIC PROCESSING WASTE

D.M. Samchenko 1,
  
G.M. Kochetov 1,
 
O.V. Lastivka 1,
 
D.O. Derecha 3,
 
T.O. Prikhna 4
 

1 Kyiv National University of Construction and Architecture, Vozdukhoflotsky prospect, 31, Kyiv, 03037, Ukraine
2 I. M. Frantsevich Institute for Problems of Materials Science of the NAS of Ukraine, Omeliana Pritsaka str.,3, Kyiv, 03142, Ukraine
3 Institute of Magnetism NAS of Ukraine and MES of Ukraine, 36-b Akad. Vernadskogo blvd., Kyiv, 03142, Ukraine
4 V. Bakul Institute for Superhard Materials of the National Academy of Sciences of Ukraine, Kyiv, Ukraine
gbag@ukr.net

Powder Metallurgy - Kiev: Frantsevich Institute for Problems of Materials Science NASU, 2023, #03/04
http://www.materials.kiev.ua/article/3582

Abstract

The potential of using wastewaters from the galvanic industry treated to remove toxic heavy-metal contaminants for the manufacture of commercial products lies in the development of processes for their reuse. This research addresses the feasibility of employing galvanic waste in the production of powder coatings. Powder waste generated through the resource-saving ferritic method and electroerosion sputtering method is significantly safer for the environment than that generated through reagent methods. Coatings resulting from wastewater treatment exhibit mechanical properties that meet current industry standards. The introduction of 15 wt.% spent polyvalent iron oxide sorbent into the paint coatings enhances their mechanical performances. Specifically, the rebound strength increases from 20 to 40 cm/kg and tensile strength from 5 to 7.4 mm, the bending strength decreases from 8 to 5 mm, and the corrosion resistance of the coatings improves by 1.5 times compared to the standard samples. These improvements are attributed to the introduction of chemically and thermally stable crystalline phases possessing ferromagnetic properties into the coatings. As a result, these coatings increase shielding against electromagnetic radiation in the megahertz range by three times compared to the standard coatings. A significant outcome of this research result is the potential for reusing ferromagnetic waste from the galvanic industry in specialized materials.


GALVANIC INDUSTRY, HEAVY METALS, IRON-CONTAINING WASTE, POWDER COATINGS, SHIELDING MATERIALS