Конференції

Features of Physical and Chemical Adsorption During Interaction of Polycrystalline and Nanocrystalline Materials with Gases

В.О.Лавренко,
 
В.О.Лавренко,
 
І.О.Подчерняєва,
   
О.Д.Золотаренко
 

Інститут проблем матеріалознавства ім. І. М. Францевича НАН України , вул. Омеляна Пріцака, 3, Київ, 03142, Україна
Powder Metallurgy and Metal Ceramics - Scopus: Springer US , 2018, Т.56, #9-10
http://www.materials.kiev.ua/article/2768

Анотація

Diborides of group IV transition metals are considered in the context of the features of two types of adsorption (physical and chemical) during interaction of polycrystalline and nanocrystal materials (carbon nanotubes, highly dispersed iron powder etc.) with gases (CO2, H2O-vapor). Due to Raman scattering spectroscopy, it is established that, in the case of adsorption, only gas chemical adsorption with typical minimal distance between absorbed gas molecule and adsorbing agent surface occurs on the surfaces of all synthesized nanoparticles. It is confirmed that the reference Raman spectrum of the correspondent nanoparticles (according to the Hirsch reference book) remains in all cases. The adsorption of oxygen and nitrogen during oxidation of diborides of group IV transition metals is investigated.

https://doi.org/10.1007/s11106-018-9922-z

Translated from Poroshkovaya Metallurgiya, Vol. 56, Nos. 9–10 (517), pp. 23–33, 2017.


БОРИДИ ПЕРЕХІДНИХ МЕТАЛІВ, ВИКРИВЛЕННЯ ЕЛЕКТРОННОЇ ОБОЛОНКИ ПОВЕРХНЕВИХ АТОМІВ, ВУГЛЕЦЕВІ НАНОТРУБКИ, ЗАЛІЗНІ НАНОПОРОШКИ, НАНОМАТЕРІАЛИ, СПЕКТРОСКОПІЯ РАМАНІВСЬКОГО РОЗСІЮВАННЯ , ФІЗИЧНА АДСОРБЦІЯ, ХІМІЧНА АДСОРБЦІЯ